Explain dipole-dipole forces and their characteristics.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Dipole-dipole forces act between molecules possessing a permanent dipole. For example,$HCl$,$HF$,$CO$,$NO$,and $NH_{3}$ exhibit dipole-dipole forces.
Ends of the dipoles possess partial charges,denoted by the Greek letter delta $(\delta)$. These partial charges are always less than the unit electronic charge $(1.6 \times 10^{-19} \ C)$.
Formation of dipole-dipole forces: Neighbouring polar molecules interact with each other. Figure $(a)$ shows the electron cloud distribution in a hydrogen chloride dipole,and Figure $(b)$ shows the dipole-dipole interaction between two $HCl$ molecules.
Characteristics:
- This interaction is stronger than London dispersion forces but weaker than ion-ion interaction because only partial charges are involved.
- The attractive force decreases as the distance between the dipoles increases.
- The interaction energy is inversely proportional to the distance between polar molecules.
- Dipole-dipole interaction energy between stationary polar molecules (as in solids) is proportional to $1/r^{3}$,and that between rotating polar molecules is proportional to $1/r^{6}$,where $r$ is the distance between the polar molecules.

Explore More

Similar Questions

The dipole moment of $o-$,$p-$ and $m-$dichlorobenzene will be in the order:

Difficult
View Solution

One Debye is equal to how many coulomb meter?

Which one of the following molecules has a zero dipole moment?

Which of the following has the maximum dipole moment?

Difficult
View Solution

The most polar bond is

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo